发明申请
- 专利标题: PROCESS FOR CONTINUOUSLY PREPARING DI-C1-3-ALKYL SUCCINATES
- 专利标题(中): 连续制备DI-C 3-烷基琥珀酸酯的方法
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申请号: US14888954申请日: 2014-05-07
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公开(公告)号: US20160083328A1公开(公告)日: 2016-03-24
- 发明人: Stefanie Demming , Suman Thotla , Jens Wittenberg , Gabriele Iffland , Till Christian Brueggemann , Yvonne Hoelzl , Wolfgang Siegel , Stephan Freyer
- 申请人: BASF SE
- 优先权: EP13167052.3 20130508
- 国际申请: PCT/EP2014/059278 WO 20140507
- 主分类号: C07C67/08
- IPC分类号: C07C67/08 ; B01D3/14 ; C07C67/54
摘要:
The invention relates to a process for continuously preparing di-C1-3-alkyl succinates by reacting succinic acid with an C1-3-alkanol in the presence of a fixed-bed heterogeneous acidic esterification catalyst in a tubular reactor at a temperature in the range of from 60 to 100° C., wherein a mixture, comprising succinic acid, C1-3-alkanol, mono-C1-3-alkyl succinate, di-C1-3-alkyl succinate and water, is formed in a mixing stage and fed to the entrance of the tubular reactor, and wherein 5 to 75% of the outlet flow rate of the tubular reactor are recycled directly to the mixing stage as a recycle stream, and the molar ratio of C1-3-alkanol to succinic acid added to the mixing zone, and not including the C1-3-alkanol and succinic acid at the recycle stream, being in the range of from 2.0 to 9.5. The invention furthermore relates to a process for separating the reactor effluent of an esterification of succinic acid with an C1-3-alkanol to give di-C1-3-alkyl succinates by distillation, wherein the separation is performed in a divided wall column in which C1-3-alkanol and water are removed in a top draw of the column, di-C1-3-alkyl succinate is removed in a side draw of the column, and wherein mono-C1-3-alkyl succinate and succinic acid are removed in a bottom draw of the column.
公开/授权文献
- US09738588B2 Process for continuously preparing di-C1-3-alkyl succinates 公开/授权日:2017-08-22
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