A method for controlling a synchronizer of a vehicle is provided. The vehicle comprises an engine unit, a transmission unit configured to selectively couple with the engine unit and to couple with at least one of a plurality of wheels of the vehicle, a synchronizer configured to adjust a power transmission between the transmission unit and the wheels. The method comprises acquiring an operation mode and operation parameters of the vehicle and controlling the synchronizer to adjust the power transmission between the transmission unit and the wheels based on the operation parameters. A vehicle including a controller configured to control the synchronizer according to the method is also provided. The vehicle further includes a first motor generator configured to adjust a rotating speed of the synchronizer according to a speed of the vehicle, and a second motor generator configured to drive at least one of wheels of the vehicle.