发明申请
US20140303374A1 METHOD FOR PRODUCING COMPOUND WITH CARBONYL GROUP BY USING RUTHENIUM CARBONYL COMPLEX HAVING TRIDENTATE LIGAND AS DEHYDROGENATION OXIDATION CATALYST
有权
通过使用具有三氯甲烷配位体的碳酸氢钠复合物作为脱氢氧化催化剂生产碳化合物的方法
- 专利标题： METHOD FOR PRODUCING COMPOUND WITH CARBONYL GROUP BY USING RUTHENIUM CARBONYL COMPLEX HAVING TRIDENTATE LIGAND AS DEHYDROGENATION OXIDATION CATALYST
- 专利标题（中）： 通过使用具有三氯甲烷配位体的碳酸氢钠复合物作为脱氢氧化催化剂生产碳化合物的方法
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申请号： US14113326申请日： 2012-04-18
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公开(公告)号： US20140303374A1公开(公告)日： 2014-10-09
- 发明人: Taichiro Touge , Kunimori Aoki , Hideki Nara , Wataru Kuriyama
- 申请人： Taichiro Touge , Kunimori Aoki , Hideki Nara , Wataru Kuriyama
- 申请人地址： JP Tokyo
- 专利权人： TAKASAGO INTERNATIONAL CORPORATION
- 当前专利权人： TAKASAGO INTERNATIONAL CORPORATION
- 当前专利权人地址： JP Tokyo
- 优先权： JP2011-095728 20110422
- 国际申请： PCT/JP2012/061005 WO 20120418
- 主分类号： C07D453/02
- IPC分类号： C07D453/02 ; B01J31/22 ; C07C51/265 ; C07C51/29 ; C07C51/235 ; C07C51/255
摘要：
Provided by the present invention is a method for efficient oxidation of alcohols by using, as a catalyst for dehydrogenation oxidation, a ruthenium complex which can be easily produced and easily handled and is obtainable at a relatively low cost. The invention relates to a method of producing a compound having a carbonyl group by dehydrogenation oxidation of alcohols by using as a catalyst the ruthenium carbonyl complex represented by the following general formula (1) RuXY(CO)(L) (1) (in the general formula (1), X and Y may be the same or different from each other and represent an anionic ligand, and L represents a tridentate aminodiphosphine ligand).
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