Invention Application
- Patent Title: PROCESS FOR THE PRODUCTION OF HCFC-1233zd
- Patent Title (中): 生产HCFC-1233zd的方法
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Application No.: US13757963Application Date: 2013-02-04
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Publication No.: US20130211154A1Publication Date: 2013-08-15
- Inventor: Stephen A. Cottrell , Hsueh Sung Tung , Konstantin A. Pokrovski , Haiyou Wang , Daniel C. Merkel
- Applicant: Honeywell International Inc.
- Applicant Address: US NJ Morristown
- Assignee: Honeywell International Inc.
- Current Assignee: Honeywell International Inc.
- Current Assignee Address: US NJ Morristown
- Main IPC: C07C17/23
- IPC: C07C17/23

Abstract:
A process for the manufacture of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) at commercial scale from the reaction of HCC-240 and HF is disclosed. In one embodiment, HCC-240fa and HF are fed to a reactor operating at high pressure. Several different reactor designs useful in this process include; a stirred-tank reactor (batch and/or continuous flow); a plug flow reactor; a static mixer used as a reactor; at least one of the above reactors operating at high pressure; optionally combined with a distillation column running at a lower pressure; and combinations of the above; and/or with a distillation column. The resulting product stream consisting of 1233zd, HCl, HF, and other byproducts is partially condensed to recover HF by phase separation. The recovered HF phase is recycled to the reactor. The HCl is scrubbed from the vapor stream and recovered as an aqueous solution. The remaining organic components including the desired HCFC-1233zd are scrubbed, dried and distilled to meet commercial product specifications.
Public/Granted literature
- US08921621B2 Process for the production of HCFC-1233zd Public/Granted day:2014-12-30
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