Embodiments include luminescent phosphor compounds that include one or more emitting ions and one or more disturbing ions, and methods for their production. An emitting ion in the compound may be characterized by a first decay time constant when the emitting ion is undisturbed. However, a corresponding disturbing ion in the compound, which is different from the emitting ion, causes the emitting ion to have a pre-defined, target disturbed decay time constant that is greater than zero and less than the first decay time constant. An embodiment of an authentication system is configured to measure the decay time constant of a phosphor compound applied to an article, and to determine whether the decay time constant corresponds to a phosphor compound that includes a particular disturbing ion (e.g., in order to determine whether or not the article is authentic).