发明申请
- 专利标题: CATALYTIC PROCESS FOR PREPARING (METH)ACRYLIC ESTERS OF N-HYDROXYALKYLATED LACTAMS
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申请号: US12524587申请日: 2008-02-11
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公开(公告)号: US20100113725A1公开(公告)日: 2010-05-06
- 发明人: Hermann Bergmann , Frank Hoefer , Maximilian Angel
- 申请人: Hermann Bergmann , Frank Hoefer , Maximilian Angel
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 优先权: EP07102484.8 20070215
- 国际申请: PCT/EP2008/051586 WO 20080211
- 主分类号: C08F4/10
- IPC分类号: C08F4/10 ; C08F4/50 ; C08F4/46 ; C08F4/08
摘要:
A process for preparing (meth)acrylic esters (F) of N-hydroxyalkylated lactams, in which cyclic N-hydroxyalkylated lactams (L) in which R1 is C1-C5-alkylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles, with the proviso that R1 must not have any atom other than a carbon atom directly adjacent to the lactam carbonyl group, R2 is C1-C20-alkylene, C5-C12-cycloalkylene, C6-C12-arylene, or C2-C20-alkylene interrupted by one or more oxygen and/or sulfur atoms and/or one or more substituted or unsubstituted imino groups and/or by one or more cycloalkyl, —(CO)—, —O(CO)O—, —(NH)(CO)O—, —O(CO)(NH)—, —O(CO)— or —(CO)O— groups, where the radicals mentioned may each be substituted by aryl, alkyl, aryloxy, alkyloxy, heteroatoms and/or heterocycles, or R2—OH is a group of the formula —[Xi]k—H, k is from 1 to 50 and Xi, for each i=1 to k, may each independently be selected from the group of —CH2—CH2—O—, —CH2—CH2—N(H)—, —CH2—CH2—CH2—N(H)—, —CH2—CH(NH2)—, —CH2—CH(NHCHO)—, —CH2—CH(CH3)—O—, —CH(CH3)—CH2—O—, —CH2—C(CH3)2—O—, —C(CH3)2—CH2—O—, —CH2—CH2—CH2—O—, —CH2—CH2—CH2—CH2—O—, —CH2—CHVin-O——CHVin-CH2—O—, —CH2—CHPh-O— and —CHPh-CH2—O—, in which Ph is phenyl and Vin is vinyl, in the presence of at least one catalyst (K) selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides and metal acetylacetonates, is esterified with (meth)acrylic acid (S) or transesterified with at least one (meth)acrylic ester (D).
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