发明申请
- 专利标题: Zirconium Hydroxide
- 专利标题(中): 氢氧化锆
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申请号: US12278074申请日: 2007-01-24
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公开(公告)号: US20090005239A1公开(公告)日: 2009-01-01
- 发明人: Heather Bradshaw , Clive Butler , Hazel Stephenson
- 申请人: Heather Bradshaw , Clive Butler , Hazel Stephenson
- 申请人地址: GB Salford
- 专利权人: MAGNESIUM ELEKTRON LIMITED
- 当前专利权人: MAGNESIUM ELEKTRON LIMITED
- 当前专利权人地址: GB Salford
- 优先权: GB0602217.2 20060203
- 国际申请: PCT/GB07/00209 WO 20070124
- 主分类号: C01G25/00
- IPC分类号: C01G25/00 ; B32B3/26 ; B01J23/10 ; B01J23/02 ; B01J23/04 ; B01J21/04 ; B01J23/14 ; B01J21/08
摘要:
This invention relates to an improved amorphous zirconium hydroxide and a method for its production. The hydroxide has a surface area of at least 300 m2/g, a total pore volume of at least 0.70 cm3/g and an average pore size of between 5 nm and 15 nm, and is prepared by a process which comprises the steps of: a) preparing an aqueous solution comprising sulphate anions and a zirconium salt such that the ZrO2:SO3 ratio is 1:0.40 to 1:0.52, (b) chilling the solution to below 25° C., (c) adding an alkali in order to precipitate the amorphous zirconium hydroxide, (d) filtering and washing the precipitated zirconium hydroxide with water or an alkali to remove residual sulphate and chloride, (e) hydrothermally treating the zirconium hydroxide at a pressure of less than 3 barg, and (f) drying the zirconium hydroxide. The zirconium hydroxide of the present invention, which can be doped, is particularly useful in catalytic applications.
公开/授权文献
- US07794687B2 Zirconium hydroxide 公开/授权日:2010-09-14
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