发明申请
- 专利标题: Method For Producing Chlorine
- 专利标题(中): 氯生产方法
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申请号: US11816045申请日: 2006-02-20
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公开(公告)号: US20080159948A1公开(公告)日: 2008-07-03
- 发明人: Martin Sesing , Armin Diefenbacher , Hartwig Voss , Olga Schubert , Lothar Seidemann , Martin Karches , Thomas Grassler , Eckhard Stroefer
- 申请人: Martin Sesing , Armin Diefenbacher , Hartwig Voss , Olga Schubert , Lothar Seidemann , Martin Karches , Thomas Grassler , Eckhard Stroefer
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 优先权: DE102005008612.8 20050223
- 国际申请: PCT/EP2006/060105 WO 20060220
- 主分类号: C01B7/04
- IPC分类号: C01B7/04
摘要:
Process for preparing chlorine from hydrogen chloride, which comprises the steps: a) feeding of a stream a1 comprising hydrogen chloride and of a stream a2 comprising oxygen into an oxidation zone and catalytic oxidation of hydrogen chloride to chlorine, giving a product gas stream a3 comprising chlorine, water, oxygen, carbon dioxide and inert gases; b) cooling of the product gas stream a3 and removal of water and hydrogen chloride as aqueous hydrochloric acid, leaving a gas stream b comprising chlorine, water, oxygen, carbon dioxide and inert gases; c) optional drying of the gas stream b) to leave a gas stream c which is substantially free of water and comprises chlorine, oxygen, carbon dioxide and inert gases; d) at least partial liquefaction of the gas stream c and of a chlorine-rich recycle stream f1 comprising chlorine, oxygen and carbon dioxide by compression and cooling, giving an at least partially liquefied stream d; e) gas/liquid separation of the stream d into a gas stream e1 comprising chlorine, oxygen, carbon dioxide and inert gases and into a liquid stream e2 comprising chlorine, oxygen and carbon dioxide; f) feeding of at least part of the gas stream e1 into a membrane separation unit and fractionation by membrane separation to give the chlorine-rich recycle stream f1 and a gas stream f2 which is low in chlorine and comprises chlorine, oxygen and carbon dioxide and recirculation of the chlorine-rich recycle stream f1 to step d); g) separation of the liquid stream e2 by distillation into a chlorine stream g1 and a stream g2 comprising essentially oxygen and carbon dioxide.
公开/授权文献
- US08097232B2 Method for producing chlorine 公开/授权日:2012-01-17
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