发明申请
- 专利标题: Method for producing high purity terephthalic acid
- 专利标题(中): 生产高纯对苯二甲酸的方法
-
申请号: US10574273申请日: 2004-09-30
-
公开(公告)号: US20070015935A1公开(公告)日: 2007-01-18
- 发明人: Hideaki Fujita , Hiroshi Machida , Nobuo Namiki , Yoshio Waguri
- 申请人: Hideaki Fujita , Hiroshi Machida , Nobuo Namiki , Yoshio Waguri
- 优先权: JP2003-344002 20031002
- 国际申请: PCT/JP04/14772 WO 20040930
- 主分类号: C07C51/16
- IPC分类号: C07C51/16 ; C07C51/42 ; C07C51/255
摘要:
In the process for producing a high-purity terephthalic acid of the invention, a slurry of crude terephthalic acid crystals dispersed in an acetic acid solvent, which is produced by a liquid-phase oxidation of p-alkylbenzene in the acetic acid solvent, is continuously converted into a slurry in water by a mother liquor displacement and then subjected to a catalytic hydrogenation. The acetic acid solvent slurry is introduced into a column equipped with a central shaft having a plurality of stirring blades along a vertical direction thereof from an upper portion of the column. The crude terephthalic acid crystals are allowed to sediment to form a high-concentration zone of terephthalic acid crystals in the column. A displacing water is fed into the column from a bottom portion thereof so as to form an upward flow of water in the column while forming circular flows in the high-concentration zone by rotation of the stirring blades, thereby bringing the terephthalic acid crystals into counter-current contact with the upward flow of water. The terephthalic acid crystals after counter-current contact with the upward flow of water is discharged from a bottom portion of the column together with the displacing water, while simultaneously taking the acetic acid solvent out of a portion of the column disposed above a feed portion for introducing the acetic acid solvent slurry. By the process, the acetic acid solvent of the acetic acid slurry is displaced by water in a high degree of mother liquor displacement.
公开/授权文献
- US07262323B2 Method for producing high purity terephthalic acid 公开/授权日:2007-08-28
信息查询