An electrode material of a fibrous structure has a platinum-based electrocatalytic material, an electrospinning polymer material, and an oxide material and/or one or more organophosphorus acid material with ion conduction. In the micromorphology has the structure of nanofibers, but also has porous morphological characteristics, the electrode material of this structure is prepared by electrostatic spinning technology, can be used as a high-temperature polymer electrolyte membrane fuel cell porous electrode.