- 专利标题: Catalyst for producing ethylene oxide by gas-phase oxidation
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申请号: US17285799申请日: 2019-09-19
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公开(公告)号: US12121881B2公开(公告)日: 2024-10-22
- 发明人: Andrey Karpov , Marco Oskar Kennema , Nicolas Duyckaerts , Christian Walsdorff , Christian Bartosch , Juergen Zuehlke , Miguel Angel Romero Valle
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen am Rhein
- 代理机构: Faegre Drinker Biddle & Reath LLP
- 优先权: EP 200499 2018.10.15
- 国际申请: PCT/EP2019/075187 2019.09.19
- 国际公布: WO2020/078657A 2020.04.23
- 进入国家日期: 2021-04-15
- 主分类号: B01J23/68
- IPC分类号: B01J23/68 ; B01J21/04 ; B01J35/40 ; B01J35/56 ; B01J35/61 ; B01J35/63 ; B01J35/64 ; B01J35/66 ; B01J37/02 ; B01J37/08 ; C07D301/04
摘要:
A shaped catalyst body for producing ethylene oxide by gas-phase oxidation of ethylene, comprising silver deposited on a porous refractory support, the shaped catalyst body having a first face side surface, a second face side surface and a circumferential surface, characterized by a content of at least 20 wt.-% of silver, relative to the total weight of the shaped catalyst body; a multilobe structure; a plurality of passageways extending from the first face side surface to the second face side surface, outer passageways being arranged around a central passageway with one outer passageway being assigned to each lobe, wherein neighboring outer passageways are arranged essentially equidistantly to each other and the outer passageways are arranged essentially equidistantly to the central passageway; a minimum wall thickness A between two neighboring passageways in the range of 0.6 to 1.3 mm; a minimum wall thickness B between each outer passageway and the circumferential surface in the range of 1.1 to 1.8 mm; and a BET surface area in the range of 1.6 to 3.0 m2/g. The shaped catalyst bodies allow for a favorable balance between mechanical stability, pressure drop and selectivity. The invention also relates to a process for producing ethylene oxide by gas-phase oxidation of ethylene, comprising reacting ethylene and oxygen in the presence of a shaped catalyst body as defined above. The invention further relates to a process for preparing a shaped catalyst body as above, comprising i) impregnating a refractory support having a BET surface area in the range of 1.4 to 2.5 m2/g with a silver impregnation solution; and ii) subjecting the impregnated refractory support to a calcination process; wherein steps i) and ii) are optionally repeated.
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