- 专利标题: Method for preferentially recovering manganese from waste lithium-rich manganese-based cathode material
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申请号: US18507242申请日: 2023-11-13
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公开(公告)号: US12119464B2公开(公告)日: 2024-10-15
- 发明人: Dean Pan , Xiaoguang Zhang , Yifan Wang , Qijun Zhang , Wei Wang
- 申请人: BEIJING UNIVERSITY OF TECHNOLOGY
- 申请人地址: CN Beijing
- 专利权人: BEIJING UNIVERSITY OF TECHNOLOGY
- 当前专利权人: BEIJING UNIVERSITY OF TECHNOLOGY
- 当前专利权人地址: CN Beijing
- 代理商 Nitin Kaushik
- 优先权: CN 2211455436.0 2022.11.21
- 主分类号: H01M10/54
- IPC分类号: H01M10/54 ; C22B1/00 ; C22B3/08 ; C22B3/22 ; C22B3/26 ; C22B7/00 ; C22B47/00
摘要:
The present invention provides a method for preferentially recovering manganese from waste lithium-rich manganese-based cathode material, the method comprising: step 1) calcination and leaching: mixing the waste lithium-rich manganese-based cathode material with ammonium sulfate and then performing low-temperature calcination, leaching the calcination product with water, and then performing solid-solution separation to obtain a leaching solution; step 2) complexing and manganese separating: adding ammonium sulfite to the leaching solution obtained in step 1) for a complex reaction to obtain manganese-rich residue; step 3) oxidation leaching: adding an oxidant to the manganese-rich residue obtained in step 2) to perform oxidation leaching, and adjusting the pH of the solution to obtain a manganese-rich solution; and step 4) extracting and stripping. The method realizes the preferential and productive recovering of manganese from waste lithium-rich manganese-based cathode materials, avoids the negative impact of polymetals in the conventional recovery process, and has economic and environmental benefits.
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