- 专利标题: Method for manufacturing ammonia synthesis catalyst, and method for manufacturing ammonia
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申请号: US16323745申请日: 2017-08-08
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公开(公告)号: US11235310B2公开(公告)日: 2022-02-01
- 发明人: Hideo Hosono , Masaaki Kitano , Toshiharu Yokoyama , Jiang Li , Shigeki Kawamura , Kazuhisa Kishida
- 申请人: Tokyo Institute of Technology , Tsubame BHB Co., Ltd.
- 申请人地址: JP Tokyo; JP Tokyo
- 专利权人: Tokyo Institute of Technology,Tsubame BHB Co., Ltd.
- 当前专利权人: Tokyo Institute of Technology,Tsubame BHB Co., Ltd.
- 当前专利权人地址: JP Tokyo; JP Tokyo
- 代理机构: Christensen O'Connor Johnson Kindness PLLC
- 优先权: JPJP2016-155951 20160808
- 国际申请: PCT/JP2017/028739 WO 20170808
- 国际公布: WO2018/030394 WO 20180215
- 主分类号: B01J23/58
- IPC分类号: B01J23/58 ; B01J37/18 ; C01C1/04 ; B01J35/10 ; B01J21/04 ; B01J23/46 ; B01J37/02 ; B01J37/08
摘要:
Provided is a method for manufacturing a catalyst with which it is possible to obtain a supported metal ammonia synthesis catalyst, in which there are restrictions in terms of producing method and producing facility, and particularly large restrictions for industrial-scale producing, in a more simple manner and so that the obtained catalyst has a high activity. This method for manufacturing an ammonia synthesis catalyst includes: a first step for preparing 12CaO.7Al2O3 having a specific surface area of 5 m2/g or above; a second step for supporting a ruthenium compound on the 12CaO.7Al2O3; and a third step for performing a reduction process on the 12CaO.7Al2O3 supporting the ruthenium compound, obtained in the second step. This invention is characterized in that the reduction process is performed until the average particle diameter of the ruthenium after the reduction process has increased by at least 15% in relation to the average particle diameter of the ruthenium before the reduction process.
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