Invention Grant
- Patent Title: Method for producing ethyleneamines
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Application No.: US16619987Application Date: 2018-05-24
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Publication No.: US11214535B2Publication Date: 2022-01-04
- Inventor: Regine Helga Bebensee , Thomas Heidemann , Barbara Becker , Eva Koch , Hermann Luyken , Johann-Peter Melder
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen am Rhein
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen am Rhein
- Agency: Faegre Drinker Biddle & Reath LLP
- Priority: EP17175151 20170609
- International Application: PCT/EP2018/063589 WO 20180524
- International Announcement: WO2018/224315 WO 20181213
- Main IPC: C07C215/08
- IPC: C07C215/08 ; B01J23/46 ; B01J23/75 ; B01J8/24 ; B01J8/18 ; B01J21/02 ; B01J21/06

Abstract:
The invention relates to processes for preparing alkanolamines and ethyleneamines in the liquid phase, by reacting ethylene glycol and/or monoethanolamine with ammonia in the presence of an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, wherein the amination catalyst is obtained by reductive calcination of a catalyst precursor. The catalyst precursor here is preferably prepared by contacting a conventional or catalytic support material with one or more soluble compounds of the active metals and optionally one or more soluble compounds of added catalyst elements. The present invention further relates to a process for preparing an amination catalyst comprising one or more active metals selected from Sn and the elements of groups 8, 9, 10 and 11 of the Periodic Table of the Elements, the amination catalyst being obtained by reductive calcination of a catalyst precursor, wherein the reactor in which the catalyst precursor is reductively calcined is connected to a denox plant, and to the use of a denox plant in the preparation of amination catalysts.
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