A battery structure is disclosed. The battery structure includes a first current collector layer, a first active material layer, a spacer layer, a first plastic frame, a second active material layer and a second current collector layer. The first active material layer is disposed on the first current collector layer. The spacer layer is disposed on the first active material and completely covers the top surface of the first active material layer. The first plastic frame is disposed on the side wall of the spacer layer and the top of the first plastic frame has a protruding part which extends to the top surface of the spacer. The second active material layer is disposed on the spacer layer and the protruding part. The second active material is isolated from the first active material via the space layer and the protruding part. The second current collector layer is disposed on the second active material layer.