Invention Grant
- Patent Title: Copolyester resin and polyester film for covering metal plates and laminated polyester film comprising same made into film
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Application No.: US14902609Application Date: 2013-07-05
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Publication No.: US11046864B2Publication Date: 2021-06-29
- Inventor: Takashi Kimiduka , Yuji Takeuchi , Junji Matsumura , Masaya Okimoto , Keita Katsuma , Hideaki Tomura , Sadamu Nakatsuka
- Applicant: DAIWA CAN COMPANY , Bell Polyester Products, Inc.
- Applicant Address: JP Tokyo; JP Yamaguchi
- Assignee: DAIWA CAN COMPANY,Bell Polyester Products, Inc.
- Current Assignee: DAIWA CAN COMPANY,Bell Polyester Products, Inc.
- Current Assignee Address: JP Tokyo; JP Yamaguchi
- Agency: Rankin, Hill & Clark LLP
- International Application: PCT/JP2013/068555 WO 20130705
- International Announcement: WO2015/001679 WO 20150108
- Main IPC: C08G63/183
- IPC: C08G63/183 ; C09D167/02 ; B65D1/12 ; B65D25/14 ; B65D25/34 ; B32B27/36 ; B32B15/09 ; C08G63/199 ; C09D167/08 ; C08G63/78

Abstract:
The problem to be solved by the present invention is to provide a polyester resin excellent in various properties wherein the film formability is good, film fracture (hairs) and scraping (galling) are not easily generated in the drawing/ironing process when applied to a metal-sheet-coating polyester film, the film surface is not damaged when used as the inner-surface film for a metallic can, and the metallic can is hardly corroded (dent resistance), by dropping or external impact (denting), after a product is made by enclosing contents into the can.
The copolyester resin of the present invention is characterized by comprising, as the constituent units, 50 to 93 mass % of (A) ester oligomer with the number-average molecular weight of 700 or lower and consisting of a dicarboxylic acid unit (a1) containing 70 mole % or more of the terephthalic acid component and a diol unit (a2) containing 70 mole % or more of the ethylene glycol component; and 7 to 50 mass % of (B) polyester polyol with the number-average molecular weight of 1500 to 3000 and consisting of a hydrogenated dimer acid unit (b1) and a 1,4-butanediol unit (b2).
The copolyester resin of the present invention is characterized by comprising, as the constituent units, 50 to 93 mass % of (A) ester oligomer with the number-average molecular weight of 700 or lower and consisting of a dicarboxylic acid unit (a1) containing 70 mole % or more of the terephthalic acid component and a diol unit (a2) containing 70 mole % or more of the ethylene glycol component; and 7 to 50 mass % of (B) polyester polyol with the number-average molecular weight of 1500 to 3000 and consisting of a hydrogenated dimer acid unit (b1) and a 1,4-butanediol unit (b2).
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