- 专利标题: Catalyst modification with alkali metal, alkaline earth metal or rare earth metal ions in the continuous liquid-phase hydrogenation of nitro compounds
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申请号: US16340593申请日: 2017-10-10
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公开(公告)号: US10538478B2公开(公告)日: 2020-01-21
- 发明人: Armin Lange de Oliveira , Barbara Wucher , Christian Bechtold , Michael Friko , Renate Hempel
- 申请人: BASF SE
- 申请人地址: DE Ludwigshafen am Rhein
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen am Rhein
- 代理机构: Oblon, McClelland, Maier & Neustadt, L.L.P.
- 优先权: EP16193137 20161010
- 国际申请: PCT/EP2017/075746 WO 20171010
- 国际公布: WO2018/069278 WO 20180419
- 主分类号: C07C209/36
- IPC分类号: C07C209/36 ; B01J23/89 ; C07C211/50 ; C07C209/82
摘要:
The present invention relates to a process for continuous hydrogenation of a nitro compound to the corresponding amine in a liquid reaction mixture comprising the nitro compound in the presence of a supported catalyst which comprises as the active component at least one element from groups 7 to 12 of the periodic table of the elements, wherein the hydrogenation is performed in the presence of at least one salt selected from the group consisting of the salts of the alkali metals, alkaline earth metals and of the rare earth metals and to a supported catalyst for continuous hydrogenation of a nitro compound to the corresponding amine in a liquid reaction mixture comprising the nitro compound which comprises as the active component at least one element from groups 7 to 12 of the periodic table of the elements and one salt of the alkali metals, alkaline earth metals or of the rare earth metals.
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