A compound and an organic optoelectronic device are provided. The compound has the chemical formula (I): wherein: X1 to X5 are independently selected from C and N, when N is selected, a substituent may not be included; R1 to R9 are independently selected nom hydrogen, deuterium, C1 to C30 alkyl, C1 to C30 heteroatom-substituted alkyl, C6 to C30 aryl, C2 to C30 heteroaryl, and a chemical group A represented by the following chemical formula (II): and at least one of R1 to R9 is selected from the chemical group A. In the chemical formula (II), R10 to R17 are independently selected from hydrogen, deuterium, C1 to C30 alkyl, C1 to C30 heteroatom-substituted alkyl, C6 to C30 aryl, and C2 to C30 heteroaryl, and Y is selected from O, S, substituted or unsubstituted imino, substituted or unsubstituted methylene, and substituted or unsubstituted silylene.