A mask frame assembly, an evaporation method and an array substrate are provided. The mask frame assembly according to the disclosure includes a frame, a covering mask and at least two evaporation masks, the evaporation masks are sequentially arranged on the frame with a gap between two adjacent evaporation masks. A first groove is arranged at a location corresponding to the gap in the frame. The first groove includes a first groove welding portion and a first groove weldless portion, the evaporation mask includes a first evaporation sub-mask corresponding to the first groove welding portion and a second evaporation sub-mask corresponding to the first groove weldless portion; and an edge of the first evaporation sub-mask and an edge of the first groove welding portion coincide.