The invention is about a method to immobilize the enzyme for environmental protection in the multiple ceram. Mix the enzyme liquid which is made up of the one or many kinds of lipase and the protease with the multiple ceram, then to stir it for 2h intermittently, infiltrate for 6h, transform for 0.5h at 2-5Pa, infiltrate for 12-24h again, the pH of the solution is 4.5-5.5 and the temperature is 10-45DEG C, the enzyme activity can reach the 2000U/MG. The material is used for disposing the waste water; it has the good efficient and stability.