The invention discloses laminated anti-scorching oil-resistant anti-static upper rubber for boots. The upper rubber is prepared from the following components in parts by weight: 60-80 parts of styrenebutadiene rubber, 40-20 parts of nitrile rubber, 1.5 parts of chloroprene rubber, 0.4-0.5 part of sulfur, 0.1-0.2 part of an accelerant M, 5 parts of zinc oxide, 4 parts of magnesium oxide, 1.5 partsof stearic acid, 1.5-2.5 parts of an anti-aging agent D, 40-50 parts of calcium carbonate, 2-5 parts of pine tar, 15 parts of dibutyl ester, 5-8 parts of black factice, 20 parts of carbon black, 8-12parts of special conductive carbon black and 0.2-0.4 part of an anti-scorching agent YG-1. According to the upper rubber, by combined use of the styrene butadiene rubber, the nitrile rubber and the chloroprene rubber, the oil resistance is better; and by properly increasing the use amount of the calcium carbonate as a filling agent, swelling resistance is facilitated. The upper rubber produced byusing a formula is better in oil resistance and relatively low in cost, can be adapted to an oil-resistant operation environment, is suitable for oil-resistant operation protection, is excellent anti-static effect and electric conduction performance, is not prone to the scorching phenomenon in the processing process and can greatly improve the safety of rubber processing.