The invention discloses a method for efficiently converting furfural to gamma-valerolactone by using POMOF catalyst synthesis and a one-pot method. In an isopropanol solvent, the one-pot method is used for converting the furfural into the gamma-valerolactone. The reaction process comprises the following steps: putting furfural, isopropanol and POMOF into a high-pressure reaction kettle, uniformlycarrying out mixing, carrying out sealing, then carrying out stirring for 1-48 hours at a temperature of 120-180 DEG C, and carrying out cooling to obtain a gamma-valerolactone solution. The catalystused in the method is cheap, is easily available, and has stable catalytic performance and good reusability. In addition, a hydrogen environment is not needed in the whole reaction, inorganic acid isnot used, and high operation safety and very good industrial application potential are achieved.