The invention provides a method for producing antimony white through high-antimony secondary smoke dust arsenic removal. According to the method, high-antimony secondary smoke dust, calcined soda anda low-temperature carbonization reducing agent are prepared, mixed and pressed into material blocks, multiple layers of coke and multiple layers of material blocks are alternately added into a blast furnace with multiple layers of tuyeres and a high-coke column with the height of 3-4 m, and the blast intensity of all the layers of tuyeres is controlled to realize reduction arsenic removal and volatilization arsenic removal of the high-coke column; a smelted alloy is charged into a refining furnace, caustic soda flakes are added for refining to remove impurities in molten alloying metal, the molten alloying metal is charged an external heating pot type low-temperature antimony white blowing furnace to be subjected to antimony white blowing; and a antimony white product is obtained through antimony white smoke cooling and cloth bag dust collection. Through the method, the alloy is obtained through reduction and smelting, and most of arsenic is removed; the production cost can be saved, and the refining direct yield of the antimony alloy can be substantially improved; the quality index of the produced antimony white meets the national standard for antimony trioxide; production of thehigh-grade antimony white from the high-antimony secondary smoke dust with high arsenic and lead content becomes beneficial and feasible, and the production cost of the high-grade antimony white is reduced.