The invention relates to a skin oil balance composite and application thereof. The skin oil balance composite comprises nicotinamide, inositol, capryloylglycine and an oil control plant extractive, wherein the oil control plant extractive comprises an chamomile extractive, an nettle extractive, a meadow pine extractive, a rosemary extractive, a melissa extractive, a buckeye seed extractive, a salvia extractive and a coltsfoot extractive. The skin oil balance composite aims at the problems of scalp oil, pruritus, alopecia and the like of the scalp and adopts the nicotinamide, inositol, capryloylglycine and oil control plant extractive to maintain oil balance, and scalp problems can be effectively solved.