The invention discloses a method for authenticating the Qing dynasty Xinjiang red coin authenticity. The method comprises the steps of building a sampling and sample preparation technology of a Xinjiang red coin surface corrosion layer oxide; immobilizing screen-printed electrode surface corrosion layer samples; realizing oxidation product fingerprint spectrum records by solid state electroanalytical chemistry; analyzing and concluding the Xinjiang red coin authenticating basis and standards; performing Xinjiang red coin authenticity authentication according to the relevant standards. The method has the advantages that the fast authentication on the Qing dynasty Xinjiang red coin authenticity can be realized; the cost is low; the operability is high; the collection value cannot be influenced.