The invention belongs to the technical field of the production of a PE composite pipe, and relates to a production process of a pre-stressed plastic steel PE composite pipe. The method comprises the steps that a fiber is immersed and covered with thermosetting resin mixture, pultrusion and heating, a plastic steel wire is solidified under tension and rolled into a tray; a braiding machine is usedto weave the plastic steel wire into a net on the surface of a base pipe; a junction of the plastic steel wire net is glued; and a layer of PE is extruded outside the glued plastic steel wire net to produce a composite pipe. A traditional steel wire is replaced by an extruded glass wire or carbon fiber wire to produce the PE composite pipe, so that the PE composite pipe has the advantage of no rusting. On the other hand, an expansion coefficient of fiber material produced by the pultrusion process is close to the expansion coefficient of PE resin and PP resin material; the fiber material is not layered even under the tension of thermal expansion and contraction after a pipe is produced, and cannot form stress on the structure of the pipe; and the glue dispenser can be fixed at the intersection when knitted, so that the uniform distribution is guaranteed and the quality and stability of the pipe materials is guaranteed.