The invention provides an intelligently controlled wireless interconnection charging pile and a charging control method employing a mobile phone APP. A control cabinet is connected with multiple groups of power modules; the control cabinet receives connection information between one charging unit and a charged vehicle and charging configuration information, simultaneously requests power metering units and a power distribution unit to select and transfer one part of power modules in the multiple groups of power modules to form appropriate power according to the received charging configuration information and charges the charged vehicle; the multiple power metering units are connected with multiple charging units to meter the power and feed back the power to the control cabinet in a wired orwireless manner for real-time storage and recording; when the vehicle of a member customer and the vehicle of a non-member customer are charged at the same time, the control cabinet adjusts the powermetering units and the power distribution unit to preferentially charge the vehicle of the member customer; and the control process can be controlled by using the mobile phone APP, so that the intelligent charging pile which is low in installation cost and can be monitored through a mobile phone is formed to charge different vehicles.