The invention provides a manufacture process of photocatalytic membrane compound glass, and belongs to the technical field of glass. The manufacture process of the photocatalytic membrane compound glass includes preparing a water solution, with the concentration of 0.1-5wt%, of a peroxy-titanium complex system, and adding surfactants into the water solution to prepare spray liquid; evenly spreading the spray liquid to the surface of clean and dry glass, performing high-temperature calcination at the temperature of 300-700 DEG C for 20-120 minutes after surface drying, and cooling the glass to room temperature to obtain the photocatalytic membrane compound glass. The manufacture process has the advantages of conciseness in procedure, low time consumption in technological process, high efficiency, wide application to production lines of various manufacturers, low investment, excellent product performance in wear resistance, bacteria resistance and formaldehyde degradation, capability of efficiently purifying air and improving environment, soft gloss like organic gems, top grade, elegance and high attractiveness.