The invention relates to a preparation method for a solid catalyst for ozone heterogeneous oxidization and belongs to the technical field of an environment-friendly and chemical catalyst. The preparation method comprises the following steps: taking a medical stone, wollastonite, aluminum hydroxide, phosphorite, illite and ulexite porous material as a carrier; modifying the carrier by broaching with lithium hypochlorite and bis(acetylacetone) beryllium, and then adding surfactant tetradecyl tributyl ammonium chloride and performing surface activating treatment under the effect of ultrasonic wave; performing hydrothermal reaction on an ultrasonic surface activated carrier, a compound mineralizer including borax and potassium sulphate, catalytic activated assistant precursors, including isopropoxy scandium (III), tri(2,2,6,6-tetramethyl-3,5-hydrochelidonic acid) gadolinium, thulium trifluoromethane sulfonate (III) and lutetium carbonate hydrate rare-earth metal organic compound and catalytic active core component precursors, including common transition metal organic compound dicyclopentadienyl titanium substituted salicylic acid complex, zinc lactate and precious metal chemical complex hexa-nitroso rhodium trisodium and dipotassium hexachloroosmium in a hydrothermal reaction kettle under the effect of trimethylamine laurate trimethylamine ammonium chloride used as an emulsifier; drying and dewatering the reaction product; burning in a muffle furnace under a certain temperature, thereby acquiring the solid catalyst for ozone heterogeneous oxidization.