The present invention provides a preparation method of two vinyl BINAP(2,2,-bis(diphenylphosphino)-1,1,-binaphthyl) derivative ligands, a preparation method of a related polymer, and applications of the related polymer as a catalyst carrier in an asymmetric catalytic reaction, and belongs to the fields of novel ligand preparation, material synthesis and applications, wherein the vinyl ligands are 4,4'-divinyl-BINAP derivative and 5,5'-divinyl-BINAP derivative and can maintain the unchanged chirality of the original BINAP ligand, the polymer is a polymer containing the chiral ligand, and the preparation method comprises that a series of vinyl-containing monomers and the vinyl BINAP ligands are subjected to copolymerization to obtain the porous polymer material having the specific surface area of up to 1700 m<2>/g and the controllable pore size range of 0.3-100 nm. According to the present invention, with the application of the polymer as the asymmetric catalyst carrier, good activity and good stability are provided.