The invention discloses an identification system and method for wireless communication between a charging station and an electric vehicle. All that is required is to install first communication equipment on the charging station and install second communication equipment on the electric vehicle, when a charging gun in the charging station is plugged into a charging jack of the electric vehicle, a first wireless communication module and a second wireless communication module search each other and are connected for communication, the first communication equipment acquires electric vehicle identity information in the second communication equipment and performs matching automatically, the charging gun is controlled by a control circuit board to charge the electric vehicle only after matching success, charging is stopped automatically after charging completion, related information in the first communication equipment and the second communication equipment is updated synchronously, and charging quantity is recorded and corresponding amount of money is deducted. The whole process is finished automatically, time and labor are saved, card swiping is not needed during each charging, convenience, fastness and more intelligence are realized, and worry about inconvenience in charging for personal or group charging due to loss of a charging card is not needed.