The invention provides an alkali-free glass fiber modified polypropylene recycling material and a preparation method of the alkali-free glass fiber modified polypropylene recycling material. The alkali-free glass fiber modified polypropylene recycling material is prepared from the following components by mixing, extruding and granulating: 30 to 75 parts of a polypropylene recycling material, 10 to 30 parts of polypropylene, 5 to 15 parts of polypropylene grafted maleic anhydride, 10 to 25 parts of alkali-free glass fiber, 0.2 to 1 part of an antioxygen and 0.5 to 2 parts of 2,5-dimethyl-2,5-bi(tert-butylperoxy)hexane. According to the alkali-free glass fiber modified polypropylene recycling material, the polypropylene grafted maleic anhydride is added into the polypropylene recycling material to introduce a strong-polarity reactive group, so that the material has high polarity and reactivity, and the compatibility of the polypropylene and the fibers is extremely improved; meanwhile, the 2,5-dimethyl-2,5-bi(tert-butylperoxy)hexane is combined so that the strength, adhesive force and dispersion performance of the material are improved; good dispersity, compatibility and excellent rigid-tough balance are obtained.