The present invention relates to a method of manufacturing a pavement structure comprising the steps of applying a chaotic laminate comprising an adherent composition comprising at least one solid epoxy resin and at least one thermoplastic polymer in a solid state at room temperature to a composition comprising a carrier structure , preferably on a concrete structure; and applying an asphalt-based carrier layer. The method can quickly and efficiently produce a pavement structure with improved adhesion of the asphalt to the substrate. It is sometimes no longer necessary to pretreat the surface with a primer.