The invention relates to a continuous casting process for producing high-titanium wear-resisting steel on a straight arc slab continuous casting machine. The continuous casting process comprises the following steps of: adopting full-protection casting for continuous casting, adopting long nozzle shielding argon gas casting from a steel ladle to a tundish and adopting immersion type water gap protection casting from the tundish to a crystallizer, wherein molten steel in the tundish adopts an alkaline covering agent and a tundish slag double-layer covering agent; adopting an eddy current probe to detect the liquid surface of the crystallizer in a fully-automatic manner in a casting process, and automatically controlling continuous-casting speed according to degree of superheat of the tundish; enabling protective slag on the surface of the crystallizer to be adaptive to high-titanium molten steel; and adopting a mode of quickly cooling the front part and slowly cooling the middle part and the rear part for a secondary cooling region of the crystallizer. According to the continuous casting process, secondary oxidization of molten steel in the casting process can be effectively prevented, stability of titanium in the molten steel is guaranteed, and the protective slag is prevented from being denatured; and meanwhile, separation of large-particle titanium compounds in steel can be restrained by optimizing and cooling, so that the problems that titanium compound particles in die casting are relatively great and are not even in distribution are solved, and the titanium compounds in the steel are guaranteed to be fine and uniformly distributed.