The invention discloses a mobile multi-energy coupled thermoelectric composite energy station with a real-time control system, and belongs to the technical field of energy utilization. The energy station comprises a power generation device in which all kinds of complementary energy is integrated. The power generation device is connected with a storage battery and an inverter through an electric energy controller. The inverter is connected with user loads. Waste heat generated by the power generation device is connected with a user heat supply device through a water circulation pipeline and through heat exchange. System controllers are connected with the power generation device and electromagnetic valves, and control the power generation device and the electromagnetic valves according to outdoor weather conditions and the demand of the user heat supply device and user loads. According to the energy station, solar energy, wind energy, biomass energy and gas are utilized fully; the equipment and dynamic operation modes of various sub-systems are optimized; the usage of the non-renewable energy is reduced; by utilization of the two system controllers, the energy can be supplied according to the weather and the demand features; the heat is provided for a user by full utilization of the waste heat generated by power generation; the system efficiency is improved; energy supply can be realized first time; and the energy using problem of a special area can be effectively solved.