The invention relates to a preparation method of methylphenylcarbamate. The preparation method comprises 1, adding urea and aniline into a pre-reactor and a diphenyl urea synthesis reactor and synthesizing diphenyl urea, 2, conveying the reaction liquid into a falling film evaporator and an evaporating crystallizer through a feeding pump, separating aniline, mixing the aniline and methanol, feeding the mixture into an alcoholysis reactor, carrying out a reaction process, feeding the reaction materials into a flash evaporation pot, separating a part of methanol and aniline and separating residual methanol and most of aniline through the falling film evaporator to obtain a methylphenylcarbamate crude product, and 3, feeding the methylphenylcarbamate crude product into a scraped film type molecule distillation device and further separating the residual microscale aniline and high-boiling residues so that high purity methylphenylcarbamate is obtained and has purity greater than or equal to 99.9%. The preparation method effectively improves methylphenylcarbamate synthesis efficiency and has a product yield greater than or equal to 98.0%. The preparation method is simple and easy and provides an effective synthesis and separation method of a phenyl carbamate intermediate used in preparation of diphenylmethane diisocyanate through the non-phosgene way.