The invention discloses a pair of anti-scalding working gloves. Each glove comprises an outer glove layer (2) and a detachable inner glove layer, wherein the outer glove layer (2) comprises a palm surface, a back surface and a finger cover integrally connected with the palm surface and the back surface; the palm surface is formed by integrally weaving flame-retardant fabric or obtained through flame retardant treatment of common fabric after the common fabric is woven; the finger cover is an integrated finger cover which can integrally accommodate all fingers, and a turnable finger cover turning cover (1) is arranged at the top end of the finger cover; the inner glove layer adopts a multilayer structure including a bonding layer (4), a thermal insulation layer (5) and an anti-scalding layer (6) from outside to inside, the bonding layer (4) is connected with the outer layer, the thermal insulation layer (5) has a good thermal insulation property, and the anti-scalding layer (6) contains substances gasified when contacting with heat; an air storage bag (3) which communicates with the anti-scalding layer (6) and has a common airtight outer surface is further arranged on the back surface of the glove. The pair of anti-scalding working gloves has the advantages of flame retardance of the surface, effective thermal insulation and scalding resistance, convenience in mounting and dismounting of the inner layer, low use cost, continuous operation and the like.