The invention discloses a high-hydrophilicity high-wear-resistance organic/inorganic hybrid photocuring paint composition. The composition comprises 60-75 parts of hydrophilic photocuring low polymer, 5-15 parts of high-functionality photocuring resin, 12-20 parts of reactive diluent, 4-6 parts of photoinitiator, 0.01-0.5 part of assistant and 0.4-2 parts of inorganic functional additive. The inorganic functional additive is selected from polyvinyl silsesquioxane, methylacryloyloxy silsesquioxane and acryloyloxy silsesquioxane. The ultraviolet-curing hydrophilic paint disclosed by the invention can be applied to a glass surface; and the cured paint has the advantages of excellent hydrophilicity, excellent physical properties, favorable adhesive force, favorable water resistance, favorable acid resistance and favorable wear resistance.