The invention provides a composite detection electrode structure and a detection apparatus of a super capacitance monomer. The composite detection electrode structure comprises a capacitance detection electrode and a resistance detection probe. The resistance detection probe is embedded in the capacitance detection electrode, and can extend out of the capacitance detection electrode. An insulating layer is disposed between the capacitance detection electrode and the resistance detection probe. The composite detection electrode structure and the detection apparatus of a super capacitance monomer is advantageous in that the value of the capacitance monomer can be detected through the capacitance detection electrode, and the resistance of the super capacitance monomer can be detected through the resistance detection probe; the insulating layer is disposed between the capacitance detection electrode and the resistance detection probe, and thereby the resistance and the value of the super capacitance monomer can be detected simultaneously; detection efficiency of the super capacitance monomer can be improved, and the interference of the resistance of the detection electrode to the resistance of the super capacitance monomer can be reduced, and the detection accuracy of the resistance of the super capacitance monomer can be increased.