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发明公开
CN104530092A 具有催化4-吡啶苯硼酸的氧醚双三唑铜配合物及其制备方法 失效 - 权利终止

具有催化4-吡啶苯硼酸的氧醚双三唑铜配合物及其制备方法
摘要：
本发明公开了一种[Cu(L)2(NO3)2] (1) (L = 1-(4-(4-(1H-1,2,4-三氮唑-1-基)苯氧基)苯基)-1H-1,2,4-三氮唑)的制备方法及作为催化4-吡啶苯硼酸偶联反应具有潜在的应用价值。它是采用“常温挥发法”，即Cu(NO3)2和L常温搅拌挥发条件下来制备该配合物。本发明进一步公开了[Cu(L)2(NO3)2] (1) (L = 1-(4-(4-(1H-1,2,4-三氮唑-1-基)苯氧基)苯基)-1H-1,2,4-三氮唑)可作为4-吡啶苯硼酸的偶联反应催化剂方面的应用。
摘要（英）：

The invention discloses a preparation method of [Cu(L)2(NO3)2] (1) (L=1-(4-(4-(1H-1,2,4-triazole-1-yl) phenoxyl) phenyl)-1H-1,2,4-triazole), and the [Cu(L)2(NO3)2] (1) (L=1-(4-(4-(1H-1,2,4-triazole-1-yl) phenoxyl) phenyl)-1H-1,2,4-triazole) has a potential application value of catalyzing a coupling reaction of 4-pyridine phenylboronic acid. A normal temperature evaporation method is adopted, namely, the complex is prepared from Cu(NO3)2 and L under a normal temperature stirring volatilization condition. The invention further discloses an application of the [Cu(L)2(NO3)2] (1) (L=1-(4-(4-(1H-1,2,4-triazole-1-yl) phenoxyl) phenyl)-1H-1,2,4-triazole) serving as a coupling reaction catalyst of the 4-pyridine phenylboronic acid.

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