The invention provides a scraper rectifying column and process for refining adiponitrile. The scraper rectifying column comprises a column body and a liquid blanking pipe, as well as a scraper evaporator, a material circulating hole, a liquid phase outlet and a circulating pump, wherein the tower body internally comprises a filler layer and a plate type layer; the scraper evaporator is mounted at the outer part of the column body in a sealing manner and below the last column plate of the plate type layer; the material circulating hole is formed in the plate type layer and outside the column body; the liquid phase outlet connected with the material circulating hole through the circulating pump is formed in the bottom part of the tower body. The scraper rectifying column and process for refining adiponitrile have the beneficial effects that a special column structure is adopted, adiponitrile is separated from other dissolved foreign matters by adopting a crystal separation method, and thus the adiponitrile product can be recovered to the maximum while high-purity adiponitrile products are obtained, the problem of coking and blocking at the bottom part of a traditional rectifying column can be effectively solved, the purity of the product is improved, and the adiponitrile products can be recovered to the maximum.