The invention provides an optical fiber and a method of manufacturing the optical fiber preform. A method for manufacturing an optical fiber preform that includes preparing a glass cylinder with inner and outer surfaces forming at least part of a cladding portion are repeatedly polished, and a glass core rod that includes a core portion having a higher refractive index than the cladding portion; and inserting the core rod into the glass cylinder and heating the glass cylinder and core rod to form a single body. The repeated polishing of the inner surface of the glass cylinder includes passing pure water that does not contain a cutting fluid over the inner surface for at least the final polishing. The polishing is preferably performed using a polishing cloth to which are affixed diamond abrasive grains. The glass core rod and the glass cylinder are preferably formed of composite quartz glass.