The invention provides a digital-to-analog converter and a code mapping method applied to the digital-to-analog converter. The digital-to-analog converter includes an operational amplifying circuit, a switched capacitor circuit, an R-string sub-circuit, and a direct-charge transfer circuit. The operational amplifying circuit has a pair of differential input ends and a pair of differential output ends. The switched capacitor circuit is coupled to the pair of differential input ends of the operational amplifying circuit. The R-string sub-circuit is coupled to the switched capacitor circuit and the pair of differential input ends of the operational amplifying circuit. The direct-charge transfer circuit is coupled to the pair of differential input ends and the pair of differential output ends of the operational amplifying circuit. The speed rate is increased, the power consumption is reduced without increasing the number of the required capacitor.