The invention provides a honeycomb catalyst for catalytically incinerating sulfur recovery tail gases and a preparation method. The catalyst is a honeycomb monomer and comprises the following active ingredients by weight percent: 1.0-15% of oxide of vanadium, 1.0-12.0% of oxide of iron and 73-98% of oxide of titanium. The preparation method is characterized by dipping vanadium and iron on a honeycomb titanium dioxide carrier. The catalyst has the characteristics of high performance, low cost, simple adaptable process, high removal rates of hydrogen sulfide and carbonyl sulfide and the like, and can be used for incinerating compounds in the sulfur recovery tail gases or other waste gases, such as hydrogen sulfide, carbon disulfide, carbonyl sulfide and the like.