The invention discloses a weeding composition containing penoxsulam and bensulfuron-methyl, which comprises active ingredient a and active ingredient b, wherein the active ingredient a is penoxsulam, the active ingredient b is bensulfuron-methyl, the weight ratio of the a to the b is 1-90:90-1; preferably, the weight ratio of the a to the b is 1-50:50-1, and particularly preferred, the weight ratio of the a to the b is 1-10:10-1. The active ingredients of the composition account for 8 to 95 percent of the total weight of the composition, and the balance is agriculturally acceptable pesticide adjuvant.