The invention relates to a connecting material for cold-transferring printing paper. The connecting material comprises an acrylic acid series coating agent composition as an insulating layer and an acrylic acid series coating agent composition as an ink bearing layer, wherein, the acrylic acid series coating agent composition as the insulating layer comprises the following compositions according to the total weight of the combination: 20 to 30 percent of acrylic acid series resin, 60 to 77 percent of solvent, 2 to 8 percent of toughener and 0.2 to 2 percent of filler; and the acrylic acid series coating agent composition as the ink bearing layer comprises the following compositions according to the total weight of the composition: 15 to 30 percent of acrylic acid series monomer, 15 to 23 percent of modified starch, 5 to 8 percent of emulsifier, 0.5 to 1.2 percent of wetting agent, 0.3 to 0.6 percent of emulsification type surface active agent, 0.4 to 0.9 percent of evocating agent, 0.001 to 0.01 percent of cross linker, 0.12 to 0.15 percent of reaction terminating agent and the residual percent to 100 percent of water. The invention also relates to a method for preparing the connecting material for the cold-transferring printing paper, the cold-transferring printing paper and a method for printing textile by using the cold-transferring printing paper.